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U.S. Department of
LaborOccupational Safety & HealthAdministration
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OSHA/EPA Occupational Chemical Database
Chemical IdentificationChemical Name: GASOLINE
CAS #: 8006-61-9 UN No: 1203 Formula:
Synonyms: Motor fuel; Motor spirits; Natural gasoline; Petrol [Note: A complex mixtur
hydrocarbons (paraffins; cycloparaffins & aromatics).]
Physical Properties
Physical Description: Clear liquid with a characteristic odor.
BP: 102F MW: 72 (approx)LEL:
1.4%NFPA Fire Rating: 3
FRZ/MLT: FRZ: NA VP: 38-300 mmHgUEL:
7.6%NFPA Health Rating: 1
FP: -45F VD: NA NFPA Reactivity Rating: 0
Sp. GR: (60F):0.72-0.76
IP: NA NFPA Sp. Inst.: NA
Exposure Limits
OSHA NIOSH Related Information
PEL-TWA ppm: NA REL-TWA ppm: NA AIHA Emergency Resp
Guidelines - ERPG-1/E
3:
NA
PEL-TWA mg/m3: NA REL-TWA mg/m3: NA
PEL-STEL ppm: NA REL-STEL ppm: NA
PEL-STEL mg/m3: NA REL-STEL mg/m3: NAPEL-C ppm: NA REL-C ppm: NA
PEL-C mg/m3: NA REL-C mg/m3: NA Carcinogen Classificati
NIOSH-Ca, TLV-A3Skin Notation: No Skin Notation: No
Notes: NANotes: CARCINOGEN (Ca);
LOQ 15 ppm
IDLH ppm: NA
IDLH mg/m3: NA
IDLH Notes: Ca
NIOSH Pocket Guide to Chemical Hazards (Current through Jun
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Gasoline CAS: 8006-
Formula: NA RTECS: LX
Synonyms & Trade Names: Motor fuel, Motor spirits, Natural gasoline,
Petrol
DOT ID &
128
Exposure Limits
NIOSH REL: Ca See Appendix A OSHA PEL : none
IDLH: Ca [N.D.] Conversion: 1 ppm = 4.5 mg/m3 (ap
Physical Description
Clear liquid with a characteristic odor.
MW: 110 (approx) BP: 102F FRZ: ? Sol: Insolu
VP: 38-300 mmHg IP: ? RGasD: NA Sp.Gr(60F)
Fl.P: -45F UEL: 7.6% LEL: 1.4% MEC: NA
Class IB Flammable Liquid (See flammable and combustible liquid classes)
Incompatibilities & ReactivitiesStrong oxidizers such as peroxides, nitric acid & perchlorates
Measurement Methods
OSHA PV2028
Personal Protection & Sanitation First Aid
Skin: Prevent skin contact
Eyes: Prevent eye contact
Wash skin: When contam
Remove: When wet (flamm)
Change: N.R.
Provide: Eyewash, Quick drench
Eye: Irr immed
Skin: Soap flush immed
Breath: Resp support
Swallow: Medical attention immed
(See procedures)
NIOSH Respirator Recommendations
NIOSH : SCBAF:PD,PP/SAF:PD,PP:ASCBA Escape: GMFOV/SCBAE
(See symbols and codes)
Exposure Routes
Inh Abs Ing Con
Symptoms
Irrit eyes, skin, muc memb; derm; head, ftg, blurred vision, dizz, slurred speech, conf,
chemical pneu (aspir liquid); possible liver, kidney damage; [carc]
(See abbreviations)
Target Organs
Eyes, skin, resp sys, CNS, liver, kidneys
(See abbreviations)
DOT Emergency Response Guidebook (ERG 2004)
Guide Number: 128
128 Flammable Liquids (Non-Polar/Water-Immiscible)POTENTIAL HAZARDS
FIRE OR EXPLOSION
* HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.
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* Vapors may form explosive mixtures with air.
* Vapors may travel to source of ignition and flash back.
* Most vapors are heavier than air. They will spread along ground and
collect in low or confined areas (sewers, basements, tanks).
* Vapor explosion hazard indoors, outdoors or in sewers.
* Those substances designated with a P may polymerize explosively when
heated or involved in a fire.* Runoff to sewer may create fire or explosion hazard.
* Containers may explode when heated.
* Many liquids are lighter than water.
* Substance may be transported hot.
HEALTH
* Inhalation or contact with material may irritate or burn skin and eyes.
* Fire may produce irritating, corrosive and/or toxic gases.
* Vapors may cause dizziness or suffocation.
* Runoff from fire control or dilution water may cause pollution.
PUBLIC SAFETY
* CALL Emergency Response Telephone Number on Shipping Paper first. IfShipping Paper not available or no answer, refer to appropriate
telephone number listed on the inside back cover.
* Isolate spill or leak area immediately for at least 25 to 50 meters
(80 to 160 feet) in all directions.
* Keep unauthorized personnel away.
* Stay upwind.
* Keep out of low areas.
* Ventilate closed spaces before entering.
PROTECTIVE CLOTHING
* Wear positive pressure self-contained breathing apparatus (SCBA).
* Structural firefighters' protective clothing will only provide limitedprotection.
EVACUATION
Large Spill
* Consider initial downwind evacuation for at least 300 meters
(1000 feet).
Fire
* If tank, rail car or tank truck is involved in a fire, ISOLATE for
800 meters (1/2 mile) in all directions; also, consider initial
evacuation for 800 meters (1/2 mile) in all directions.
EMERGENCY RESPONSE
FIRE
CAUTION: All these products have a very low flash point: Use of water spray
when fighting fire may be inefficient.
Small Fires
* Dry chemical, CO2, water spray or regular foam.
Large Fires
* Water spray, fog or regular foam.
* Use water spray or fog; do not use straight streams.
* Move containers from fire area if you can do it without risk.
Fire involving Tanks or Car/Trailer Loads
* Fight fire from maximum distance or use unmanned hose holders or
monitor nozzles.
* Cool containers with flooding quantities of water until well afterfire is out.
* Withdraw immediately in case of rising sound from venting safety
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devices or discoloration of tank.
* ALWAYS stay away from tanks engulfed in fire.
* For massive fire, use unmanned hose holders or monitor nozzles; if this
is impossible, withdraw from area and let fire burn.
SPILL OR LEAK
* ELIMINATE all ignition sources (no smoking, flares, sparks or flames
in immediate area).* All equipment used when handling the product must be grounded.
* Do not touch or walk through spilled material.
* Stop leak if you can do it without risk.
* Prevent entry into waterways, sewers, basements or confined areas.
* A vapor suppressing foam may be used to reduce vapors.
* Absorb or cover with dry earth, sand or other non-combustible material
and transfer to containers.
* Use clean non-sparking tools to collect absorbed material.
Large Spills
* Dike far ahead of liquid spill for later disposal.
* Water spray may reduce vapor; but may not prevent ignition in closed
spaces.
FIRST AID
* Move victim to fresh air.
* Call 911 or emergency medical service.
* Apply artificial respiration if victim is not breathing.
* Administer oxygen if breathing is difficult.
* Remove and isolate contaminated clothing and shoes.
* In case of contact with substance, immediately flush skin or eyes with
running water for at least 20 minutes.
* Wash skin with soap and water.
* Keep victim warm and quiet.
* Ensure that medical personnel are aware of the material(s) involved,and take precautions to protect themselves.
Additional Emergency Response Information (CAMEO Data)
Non-fire Spill Response: Keep sparks, flames, and other sources of ignition away. Ke
of water sources and sewers. Build dikes to contain flow as necessary. Attempt to stop l
undue personnel hazard. Use water spray to knock-down vapors. ( AAR, 1999)
Firefighting: Do not extinguish fire unless flow can be stopped. Use water in flooding q
fog. Solid streams of water may spread fire. Cool all affected containers with flooding q
water. Apply water from as far a distance as possible. Use foam, dry chemical, or carbo( AAR, 1999)
Reactivity: This compound is incompatible with the following:Strong oxidizers such as
acid & perchlorates (NIOSH, 1997)
First Aid: Eye: If this chemical contacts the eyes, immediately wash the eyes with larg
water, occasionally lifting the lower and upper lids. Get medical attention immediately.
should not be worn when working with this chemical. Skin: If this chemical contacts the
immediately flush the contaminated skin with soap and water. If this chemical penetrat
immediately remove the clothing and flush the skin with water. If irritation persists afte
medical attention. Breathing: If a person breathes large amounts of this chemical, mov
person to fresh air at once. If breathing has stopped, perform mouth-to-mouth resuscit
affected person warm and at rest. Get medical attention as soon as possible. Swallow: I
has been swallowed, get medical attention immediately. (NIOSH, 1997)
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